BUNSEKI KAGAKU
Print ISSN : 0525-1931
Analytical Reports
Seasonal Variation of Arsenic Concentration in Lake Water of Sakata Lagoon
Norio FUKUZAKI
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2018 Volume 67 Issue 9 Pages 557-564

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Abstract

Sakata lagoon, a sand-dammed dune lake fed by only spring water and precipitation, is located in Niigata City. The inflow water from the upper lagoon, Kami-sakata, and the outflow water to the general river, were collected biweekly 152 times over a period ranging from February 2011 to January 2017, respectively. The total arsenic (T-As) and other parameters (temperature, pH, ORP, main ionic components including HCO3, iron, and manganese) were measured. Based on the temporal variations, seasonal comparisons and factor analysis, the following conclusions were obtained: 1) The concentration of T-As increased in the warm season, and sometimes exceeded the environmental standard value of 10 μg L−1. Approximately, 80 % of the T-As is present in the soluble form. 2) The ORP of outflow water decreased during the warm seasons to approximately 86 % of that during the cold seasons. Further, during warm seasons, the concentrations of NO3 and SO42− significantly decreased, and the concentrations of HCO3 in both the inflow and outflow water remarkably increase during warm season. 3) The increase in the concentration of T-As during the warm season is considered to be caused by the reduced adsorption affinity of As onto the organic matter and/or Fe(III) hydroxide in the lake sediments. Biological activities in the sediments may induce the decomposition of organic matter and a decreased ORP; the increased concentration of HCO3 and pH occurred mainly in outflow water, which affords the following decreased adsorption affinity of As.

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© 2018 The Japan Society for Analytical Chemistry
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